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Yttrium Vanadate (YVO4) Crystal

Yttrium Vanadate (YVO4) Crystal

Introduction The Yttrium Orthovanadate (YVO4) is a positive uniaxial crystal grown with Czochralski method. It has good temperature stability and physical and mechanical properties. It is ideal for o..

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Introduction

The Yttrium Orthovanadate (YVO4) is a positive uniaxial crystal grown with Czochralski method. It has good temperature stability and physical and mechanical properties. It is ideal for optical polarizing components because of its wide transparency range and large birefringence. It is an excellent synthetic substitute for Calcite (CaCO3) and Rutile (TiO2) crystals in many applications including fiber optic isolators and circulators, interleavers, beam displacers and other polarizing optics ( refer to Table 2).

Table 1. Basic Properties of YVO4 crystal

Transparency Range
High transmittance from 0.4 to 5μm
Crystal Symmetry
Zircon Tetragonal, space group D4h
Crystal Cell
a=b=7.12Å,c=6.29Å
Density
4.22g/cm3
Mohs Hardness
5,glass-like
Hygroscopic Susceptibility
Non-hygroscopic
Thermal Expansion Coefficient
αa = 4.43×10-6/K;α= 11.37 ×10-6/K
Thermal Conductivity Coefficient
//C: 5.23 W/m/K; ⊥C: 5.10 W/m/K
Crystal Class
Positive uniaxial with  no=na=nb, ne=nc
Thermal Optical Coefficient
dna/dT = 8.5×10-6/K;dnc/dT = 3.0×10-6/K
Refractive Indices, Birefringence 
(Δn = ne- no
and Walk-off Angle @ 45° (ρ)
no = 1.9929, ne = 2.2154, Δn = 0.2225, ρ= 6.04°   at 630nm
no = 1.9500, ne = 2.1554, Δn = 0.2054, ρ= 5.72°    at 1300nm      
no  = 1.9447, ne = 2.1486, Δn = 0.2039, ρ= 5.69°    at 1550nm   
Sellmeier Equation(λ in μm)  
no2 = 3.77834 + 0.069736/(λ2 - 0.04724) - 0.0108133λ2
ne2 = 4.59905 + 0.110534/(λ2- 0.04813) - 0.0122676λ2

Table 2. Comparison of basic properties between YVO4 and other Birefringent Crystals

 
YVO4
TiO2
CaCO3
LiNbO3
Thermal Expansion ( /oC)
c-axis
11.4x10-6
9.2x10-6
26.3x10-6
16.7x10-6
a-axis
4.4x10-6
7.1x10-6
5.4x10-6
7x10-6
Refractive Index
no
1.9447@1550nm
2.454@1530nm
1.6346@ 1497nm
2.2151@ 1440nm
ne
2.1486@1550nm
2.710@1530nm
1.4774@ 1497nm
2.1413@ 1440nm
Birefringence (ne-no)
0.2039@1550nm
0.256@1530nm
-0.1572@ 1497nm
-0.0738@ 1440nm
Mohs Hardness
5
6.5
3
5
Deliquescence
None
None
Weak
None
Transparency Range
0.4-5mm
0.4-5mm
0.35-2.3mm
0.4-5mm