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Nd:YVO4 - Neodymium Doped Yttrium Orthovanadate

Nd:YVO4 - Neodymium Doped Yttrium Orthovanadate

Neodymium Doped Yttrium Orthovanadate (Nd:YVO4) is the most efficient laser host crystal for diode pumping among the current commercial laser crystals, especially, for low to middle power density. Thi..

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Neodymium Doped Yttrium Orthovanadate (Nd:YVO4) is the most efficient laser host crystal for diode pumping among the current commercial laser crystals, especially, for low to middle power density. This is mainly for its absorption and emission features surpassing Nd:YAG. Pumped by laser diodes, Nd:YVO4 crystal has been incorporated with high NLO coefficient crystals (LBO, BBO, or KTP) to frequency-shift the output from the near infrared to green, blue, or even UV. This incorporation to construct all solid state lasers is an ideal laser tool that can cover the most widespread applications of lasers, including machining, material processing, spectroscopy, wafer inspection, light displays, medical diagnostics, laser printing, and data storage, etc. It has been shown that Nd:YVO4 based diode pumped solid state lasers are rapidly occupying the markets traditionally dominated by water-cooled ion lasers and lamp-pumped lasers, especially when compact design and single-longitudinal-mode output are required.

Basic Properties of Nd:YVO4: 

Atomic Density
1.26x1020 atoms/cm3 (Nd1.0%)
Crystal Structure
Cell Parameter
Zircon Tetragonal, space group D4h-I4/amd
a=b=7.1193Å,c=6.2892Å
Density
4.22g/cm3
Mohs Hardness
4-5 (Glass-like)
Thermal Expansion Coefficient(300K)
αa=4.43x10-6/K
αc=11.37x10-6/K
Thermal Conductivity Coefficient(300K)
∥C:0.0523W/cm/K
⊥C:0.0510W/cm/K
Lasing wavelength
1064nm,1342nm
Thermal optical coefficient(300K)
dno/dT=8.5×10-6/K
dne/dT=2.9×10-6/K
Stimulated emission cross-section
25×10-19cm2 @ 1064nm
Fluorescent lifetime
90μs(1%)
Absorption coefficient
31.4cm-1 @810nm
Intrinsic loss
0.02cm-1 @1064nm
Gain bandwidth
0.96nm@1064nm
Polarized laser emission
polarization; parallel to optical axis (c-axis)
Diode pumped optical to optical efficiency
>60%
Sellmeier equations(λ in μm)
no2=3.77834+0.069736/(λ2-0.04724)-0.010813λ2
ne2=4.59905+0.110534/(λ2-0.04813)-0.012676λ2
 

Transparency Curve for Nd:YVO4 (Thickness=1mm)

YVO4

Capabilities

ATTRIBUTE
COMMERCIAL
HIGH PRECISION
OPTICAL AXIS ORIENTATION
±0.5°
±0.1°
PARALLELISM
20"
10"
PERPENDICULARITY
15'
5'
FLATNESS
λ/4
λ/10
SURFACE QUALITY
40-20 scratch and dig
10-5 scratch and dig
DIMENSION TOLERANCE
±0.1mm
±0.005mm
AR COATING
R<0.2%@1550±40nm
Specified